| 1 César | Goalkeeper | 17 Joaquín | Midfielder | |
| 13 Miguel Ángel Moyá | Goalkeeper | 18 Manuel Fernandes | Midfielder | |
| 2 Bruno | Defender | 19 Pablo Hernández | Midfielder | |
| 4 David Navarro | Defender | 21 David Silva | Midfielder | |
| 5 Marchena | Defender | 24 Ever Banega | Midfielder | |
| 11 Asier Del Horno | Defender | 28 Jordi Alba | Midfielder | |
| 15 Dealbert | Defender | 38 Vicente Romero Romero | Midfielder | |
| 20 Alexis | Defender | - Isco | Midfielder | |
| 22 Jérémy Mathieu | Defender | 7 David Villa | Striker | |
| 23 Miguel | Defender | 9 Nikola Zigic | Striker | |
| - Olcina | Midfielder | 10 Mata | Striker | |
| 3 Hedwiges Maduro | Midfielder | 25 Alejandro Domínguez | Striker | |
| 6 Albelda | Midfielder | 30 Míchel | Striker | |
| 8 Baraja | Midfielder | - Unai Emery | Manager/Coach | |
| 14 Vicente | Midfielder |
| Player | Goals | Penalties | ||
|---|---|---|---|---|
 | David Villa Valencia | A | 15 | 1 |
 | Mata Valencia | A | 5 | 0 |
 | Pablo Hernández Valencia | C | 4 | 0 |
 | David Silva Valencia | C | 3 | 0 |
 | E. Banega Valencia | C | 2 | 0 |
| Player |
To |
From |
|
|---|---|---|---|
 | A. Del Horno Defender | Valladolid | Valencia |
 | Miku Striker | Getafe | Valencia |
 | I. González Midfielder | Levadeiakos | Valencia |
 | Alejandro Domínguez Striker | Valencia | Rubin |
 | Aarón Ñíguez Striker | Celta | Valencia |
 | M. Angulo Midfielder | Sporting | Valencia |
 | Carleto Defender | Elche | Valencia |
| Sporting de Gijón - Valencia | 13/02/2010 |
| Club Brugge KV - Valencia | 18/02/2010 |
| Valencia - Getafe | 21/02/2010 |
| Valencia - Club Brugge KV | 25/02/2010 |
| Atlético de Madrid - Valencia | 28/02/2010 |
| Valencia - Racing Santander | 07/03/2010 |
| Barcelona - Valencia | 14/03/2010 |
| Valencia - Almería | 21/03/2010 |
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