| 1 Gennaro Iezzo | Goalkeeper | 11 Christian Maggio | Midfielder | |
| 22 Matteo Gianello | Goalkeeper | 15 Jesús Alberto Dátolo | Midfielder | |
| 26 Morgan De Sanctis | Goalkeeper | 17 Marek Hamsik | Midfielder | |
| 2 Gianluca Grava | Defender | 18 Mariano Adrian Bogliacino | Midfielder | |
| 6 Salvatore Aronica | Defender | 21 Luca Cigarini | Midfielder | |
| 8 Andrea Dossena | Defender | 23 Walter Gargano | Midfielder | |
| 13 Fabiano Santacroce | Defender | 32 Nicolas Amodio | Midfielder | |
| 14 Hugo Armando Campagnaro | Defender | 91 Raffaele Maiello | Midfielder | |
| 16 Juan Camilo Zúñiga | Defender | 7 Ezequiel Iván Lavezzi | Striker | |
| 28 Paolo Cannavaro | Defender | 9 Erwin Hoffer | Striker | |
| 33 Erminio Rullo | Defender | 19 Germán Gustavo Denis | Striker | |
| 77 Leandro Rinaudo | Defender | 27 Fabio Quagliarella | Striker | |
| - Lorenzo Insigne | Midfielder | - Walter Mazzarri | Manager/Coach | |
| 5 Michele Pazienza | Midfielder |
| Player | Goals | Penalties | ||
|---|---|---|---|---|
 | M. Hamsik Napoli | C | 8 | 1 |
 | F. Quagliarella Napoli | A | 7 | 0 |
 | C. Maggio Napoli | C | 6 | 0 |
 | E. Lavezzi Napoli | A | 4 | 0 |
 | G. Denis Napoli | A | 3 | 0 |
| Player |
To |
From |
|
|---|---|---|---|
 | M. Contini | Zaragoza | Napoli |
 | A. Dossena Defender | Napoli | Liverpool |
 | I. Pià Striker | Torino | Napoli |
 | F. Montervino Midfielder | Salernitana | Napoli |
 | M. Blasi Midfielder | Palermo | Napoli |
 | M. Zalayeta Striker | Bologna | Napoli |
 | L. Vitale Midfielder | Livorno | Napoli |
| Napoli - Inter Milan | 2/14/10 |
| Siena - Napoli | 2/21/10 |
| Napoli - Roma | 2/28/10 |
| Bologna - Napoli | 3/7/10 |
| Napoli - Fiorentina | 3/14/10 |
| Milan - Napoli | 3/21/10 |
| Napoli - Juventus | 3/24/10 |
| Napoli - Catania | 3/28/10 |
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